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/ Wednesday, October 08, 2008
[Federal Register: October 8, 2008 (Volume 73, Number 196)]
[Proposed Rules]
[Page 58913-58922]
From the Federal Register Online via GPO Access [wais.access.gpo.gov]
[DOCID:fr08oc08-29]
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ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 52
[EPA-R07-OAR-2008-0538; FRL-8726-8]
Approval and Promulgation of Implementation Plans; State of
Missouri
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
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SUMMARY: The Environmental Protection Agency (EPA) is proposing to
grant conditional approval of Missouri's attainment demonstration State
Implementation Plan (SIP) for the lead National Ambient Air Quality
Standard (NAAQS) nonattainment area of Herculaneum, Missouri. The state
asserts that it will adopt and submit specific enforceable measures to
EPA by date certain, which will be no later than one year following any
EPA approval of the plan, in order to meet the conditions described in
this proposal. EPA proposes conditional approval because Missouri's SIP
submission provides substantial progress toward improving air quality,
and Missouri has committed to submitting a SIP revision to meet all
applicable requirements of the Clean Air Act.
DATES: Comments must be received on or before November 7, 2008.
ADDRESSES: Submit your comments, identified by Docket ID No. EPA-R07-
OAR-2008-0538, by one of the following methods:
1. http://www.regulations.gov: Follow the on-line instructions for
submitting comments.
2. E-mail: yoshimura.gwen@epa.gov.
3. Mail, Hand Delivery or Courier: Gwen Yoshimura, Environmental
Protection Agency, Air Planning and Development Branch, 901 North 5th
Street, Kansas City, Kansas 66101.
Instructions: Direct your comments to Docket ID No. EPA-R07-OAR-
2008-0538. EPA's policy is that all comments received will be included
in the public docket without change and may be made available online at
http://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through http://
www.regulations.gov or e-mail. The http://www.regulations.gov Web site
is an ``anonymous access'' system, which
[[Page 58914]]
means EPA will not know your identity or contact information unless you
provide it in the body of your comment. If you send an e-mail comment
directly to EPA without going through http://www.regulations.gov, your
e-mail address will be automatically captured and included as part of
the comment that is placed in the public docket and made available on
the Internet. If you submit an electronic comment, EPA recommends that
you include your name and other contact information in the body of your
comment and with any disk or CD-ROM you submit. If EPA cannot read your
comment due to technical difficulties and cannot contact you for
clarification, EPA may not be able to consider your comment. Electronic
files should avoid the use of special characters, any form of
encryption, and be free of any defects or viruses.
Docket. All documents in the electronic docket are listed in the
http://www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, will be publicly available only in hard copy.
Publicly available docket materials are available either electronically
in http://www.regulations.gov or in hard copy at the Environmental
Protection Agency, Air Planning and Development Branch, 901 North 5th
Street, Kansas City, Kansas. EPA requests that you contact the person
listed in the FOR FURTHER INFORMATION CONTACT section to schedule your
inspection. The interested persons wanting to examine these documents
should make an appointment with the office at least 24 hours in
advance.
FOR FURTHER INFORMATION CONTACT: Gwen Yoshimura at (913) 551-7073, or
e-mail her at yoshimura.gwen@epa.gov.
SUPPLEMENTARY INFORMATION: Throughout this document ``we,'' ``us,'' or
``our'' refer to EPA.
Table of Contents
I. Background
A. The SIP Process
1. What is a SIP?
2. What is the Federal approval process for a SIP?
3. What does Federal approval of a state regulation mean to me?
B. Background for the Proposal
II. Technical Review of the Submittal
A. Summary of the State Submittal
1. Facility Description
2. Model Selection, Meteorological and Emissions Inventory Input
Data
3. Modeling Results
4. Control Strategy
5. Reasonably Available Control Measures (RACM) Including
Reasonably Available Control Technology (RACT)
6. Reasonable Further Progress (RFP)
7. New Source Review (NSR)
8. Contingency Measures
9. Enforceability
III. Proposed Action
IV. Statutory and Executive Order Reviews
I. Background
A. The SIP Process
1. What is a SIP?
Section 110 of the Clean Air Act (CAA or Act) requires states to
develop air pollution regulations and control strategies to ensure that
state air quality meets the national ambient air quality standards
established by EPA. These ambient standards are established under
section 109 of the CAA, and they currently address six criteria
pollutants. These pollutants are: carbon monoxide, nitrogen dioxide,
ozone, lead, particulate matter, and sulfur dioxide.
Each state must submit these regulations and control strategies to
us for approval and incorporation into the Federally-enforceable SIP.
Each Federally-approved SIP protects air quality primarily by
addressing air pollution at its point of origin. These SIPs can be
extensive, containing state regulations or other enforceable documents
and supporting information such as emission inventories, monitoring
networks, and modeling demonstrations.
2. What is the Federal approval process for a SIP?
In order for state regulations to be incorporated into the
Federally-enforceable SIP, states must formally adopt the regulations
and control strategies consistent with state and Federal requirements.
This process generally includes a public notice, public hearing, public
comment period, and a formal adoption by a state-authorized rulemaking
body.
Once a state rule, regulation, or control strategy is adopted, the
state submits it to EPA for inclusion into the Federally-approved SIP.
We must provide public notice and seek additional public comment
regarding the proposed Federal action on the state submission. If
adverse comments are received, they must be addressed prior to any
final Federal action by EPA.
All state regulations and supporting information approved by EPA
under section 110 of the CAA are incorporated into the Federally-
approved SIP. Records of such SIP actions are maintained in the Code of
Federal Regulations (CFR) at Title 40, Part 52, entitled Approval and
Promulgation of Implementation Plans. The actual state regulations
which are approved are not reproduced in their entirety in the CFR
outright but are incorporated by reference, which means that EPA has
approved a given state regulation with a specific effective date.
3. What does Federal approval of a state regulation mean to me?
Enforcement of the state regulation before and after it is
incorporated into the Federally-approved SIP is primarily a state
responsibility. However, after the regulation is Federally approved,
EPA is authorized to take enforcement action against violators.
Citizens are also offered legal recourse to address violations as
described in section 304 of the CAA.
B. Background for the Proposal
The Environmental Protection Agency (EPA) established the National
Ambient Air Quality Standard (NAAQS) for lead on October 5, 1978 (43 FR
46246). The NAAQS for lead is set at a level of 1.5 micrograms (mug) of
lead per cubic meter (m\3\) of air, averaged over a calendar quarter.
During the 1980s and 1990s, Missouri submitted and EPA approved a
number of State Implementation Plan (SIP) revisions for lead to address
ambient lead concentrations in various areas of the state. One such
area was Herculaneum, Missouri, where a primary lead smelter has been
in operation since 1892. The primary lead smelter is currently owned
and operated by the Doe Run Resources Company (hereafter referred to as
``Doe Run''). Doe Run-Herculaneum is the only currently operating
primary lead smelter in the United States.
The city of Herculaneum was designated nonattainment for lead in
1991 (56 FR 56694, November 6, 1991, codified at 40 CFR 81.326),
pursuant to new authorities provided by the Clean Air Act Amendments of
1990. The state also became subject to new SIP requirements under part
D, Title I of the Act, added by the 1990 amendments. A revised SIP
meeting the part D requirements was subsequently submitted in 1994. The
plan established June 30, 1995, as the date by which the Herculaneum
area was to attain compliance with the lead standard. However, the plan
did not result in attainment of the standard and monitored ambient air
lead concentrations in the Herculaneum area continued to show
exceedances of the standard. Therefore, on August 15, 1997, after
taking and responding to public comments, EPA published a notice in the
Federal Register (62 FR
[[Page 58915]]
43647) finding that the Herculaneum nonattainment area had failed to
attain the lead standard by the June 30, 1995, deadline.
On January 10, 2001, Missouri submitted a revised SIP to EPA for
the Herculaneum area. The SIP contained control measures to reduce lead
emissions to attain the standard, including building enclosure and
ventilation projects, implementation of work practice standards,
process throughput restrictions and hours of operation limitations. As
required by section 172(c)(9) of the Act, the plan also included
contingency measures to be implemented in the event that there were
future exceedances of the lead standard in Herculaneum. These consisted
of additional building enclosures and process controls, and a
production curtailment measure. A 2000 Work Practices Manual, 2001
Consent Judgment, and Missouri rule 10 CSR 10-6.120 ``Restriction of
Emissions of Lead from Specific Lead Smelter-Refinery Installations''
were also included as part of the SIP submittal. The SIP established
August 14, 2002, as the attainment date for the area. The plan included
permitting, monitoring, and reporting requirements, an emissions
inventory, implementation of all reasonably available control measures
as expeditiously as practicable, provided for attainment of the NAAQS
as demonstrated using modeling, provisions for reasonable further
progress and implementation of contingency measures, and assurances
that the state would be able to implement the plan, thereby satisfying
the CAA section 172(c) nonattainment plan provision requirements. EPA
approved the SIP on April 16, 2002 (67 FR 18497).
Doe Run and the Missouri Department of Natural Resources (MDNR)
operate co-located monitors at the Broad Street and Main Street/City
Hall monitoring locations (in addition to other lead monitoring
locations in the nonattainment area). These monitors are used to show
whether or not the area is in attainment of the standard. Following the
August 2002 attainment date, the Herculaneum area monitored attainment
of the lead standard for 10 consecutive calendar quarters. In 2005, air
quality monitors in the area again reported exceedances of the 1.5
[mu]g/m\3\ lead NAAQS in the first two calendar quarters in 2005.
Monitored values are quality assured by MDNR and properly entered into
the Air Quality System, EPA's repository for ambient air monitoring
data. The values for the first two quarters of 2005 exceed the 1.5
[mu]g/m\3\ lead standard and, therefore, constitute exceedances of the
standard for each quarter.
Typically, an exceedance would trigger implementation of a
contingency measure. The first set of contingency measures, consisting
of additional building enclosures and process controls, was fully
implemented by Doe Run prior to any monitored exceedances of the lead
NAAQS. The second contingency measure, a production curtailment, was
implemented following exceedance of the lead standard in the first and
second calendar quarters of 2005. Despite implementation of all
contingency measures, air monitors in Herculaneum recorded values above
the 1.5 [mu]g/m\3\ lead standard in the third quarter of 2005.
Because the exceedance recorded in the third quarter of 2005
occurred despite implementation of all the control measures contained
in the SIP, including all contingency measures developed and
implemented to address exceedances, EPA proposed a SIP call on December
19, 2005 (70 FR 75093). The SIP call proposed to find the SIP
substantially inadequate to attain and maintain the NAAQS for lead and
proposed to require the state to revise the lead SIP for Herculaneum.
EPA finalized the SIP call on April 14, 2006 (71 FR 19432). The SIP
call notified the state of EPA's finding that the SIP was substantially
inadequate to provide for attainment and maintenance of the lead NAAQS
in Herculaneum, and required the state to submit a revised SIP. Section
110(k)(5) of the CAA provides that after EPA makes a finding that a
plan is substantially inadequate, it may establish a reasonable
deadline for correcting the deficiencies, but the date can be no later
than 18 months after the state is notified of the finding. Based on a
number of considerations detailed in the final rule, the SIP call
required submission of the revisions within 12 months following date of
signature of the final rulemaking.
Along with a deadline for SIP submittal by the state to EPA, the
final SIP call established the date by which the state must demonstrate
attainment of the standard in Herculaneum. Sections 110(k)(5) and
172(d) of the Act provide that EPA may adjust any SIP deadlines that
are applicable under the Act, except that the attainment date may not
be adjusted unless it has elapsed. For Herculaneum, the attainment date
had been August 2002 (five years after the state was notified that the
area failed to attain). The attainment date had elapsed, and the area
was not attaining the standard. The attainment date could therefore be
adjusted pursuant to section 110(k)(5) and section 172(d) of the Act,
and the state was required to provide for attainment as expeditiously
as practicable. Based on information described in the final SIP call
rule, EPA established an attainment date of April 7, 2008, two years
from the date of signature of the final rulemaking. MDNR formally
commented in support of the timelines contained in the SIP call,
including the SIP submittal deadline and attainment date.
EPA required MDNR to submit several specific plan elements to EPA
in order to correct the inadequacy of the SIP. These specific elements
were: (1) A revised emissions inventory, (2) a modeling demonstration
showing what reductions would be needed to bring the area back into
attainment of the lead NAAQS, (3) adoption of measures to achieve the
reductions determined necessary by the modeled attainment
demonstration, with enforceable schedules for implementing the measures
as expeditiously as practicable, and (4) contingency measures meeting
the requirements of Section 172(c)(9) of the CAA.
MDNR completed its revision to the SIP, and on April 26, 2007, the
Missouri Air Conservation Commission approved the SIP revision after
completing the required public notification, public hearing and comment
period. On May 31, 2007, EPA received Missouri's revised SIP for the
Herculaneum area. MDNR submitted supplemental information to EPA on
March 19, 2008.
Since the SIP call was issued in April 2006, Herculaneum air
monitors have recorded additional exceedances of the quarterly lead
NAAQS. In total, since the third quarter of 2002, exceedances have
occurred in the: First, second, third quarters of 2005; first, third,
fourth quarters of 2006; second and third quarters of 2007; and the
first quarter (January-March) of 2008. The SIP submittal establishes
April 7, 2008, as the attainment date and requires implementation of
all measures required for attainment by that date.
II. Technical Review of the Submittal
A. Summary of the State Submittal
This SIP builds upon technical information and tools developed
under the previous SIP, improving upon and adding to this information
to more accurately model current conditions. EPA proposed, and MDNR
agreed, that a shortened timeframe for developing the control strategy
was appropriate given the substantial amount of technical information
already available, early initiation of discussions between the source
(Doe Run) and the state, and
[[Page 58916]]
the significance of lead as a public health concern. The resulting SIP
thus builds and improves upon previous demonstrations to show
attainment under current conditions.
Several elements are typically included to produce an attainment
demonstration. A computer model is selected to predict concentrations
of the pollutant (in this case, lead) in the air under different
scenarios. The model requires input data, including an emissions
inventory for the identified sources and meteorological data for use in
simulating different weather conditions. Information such as actual
monitored concentrations and filter data may be used to assess the
model's accuracy. Finally, control measures are developed and inserted
into the model. A successful attainment demonstration shows that the
area will attain the standard if all enforceable conditions, including
the proposed control measures, are met.
The SIP must contain legally enforceable emissions limitations and
other measures necessary to attain the NAAQS as expeditiously as
practicable, as required by Section 110(a)(2) of the Act. The SIP
submitted by MDNR contains two regulatory documents: (1) The May 2007
Consent Judgment between the state of Missouri, Missouri Department of
Natural Resources (MDNR), Missouri Air Conservation Commission (MACC),
and the Doe Run Resources Company, containing control requirements,
associated implementation schedules, and contingency measures, and (2)
the January 2007 Doe Run Herculaneum Smelter Work Practices Manual
(WPM), specifying operational procedures, recordkeeping, and required
practices. Missouri rule 10 CSR 10-6.120 complements this SIP revision
and has been previously approved by EPA (see generally, 71 FR 33622,
June 12, 2006, for EPA's approval of the most recent revision). In
addition, the provisions of paragraphs (B) and (C) of the January 2001
Consent Judgment, approved as part of the 2002 SIP, remain in full
force and effect, except when inconsistent with the 2007 Consent
Judgment. MDNR has provided an explanation of the differences between
the two documents, and a justification for the changes from the 2001
Consent Judgment to the 2007 Consent Judgment. The 2001 and 2007
Consent Judgment, 2007 Work Practices Manual, and additional SIP
package documents may be found in the docket for this rulemaking. The
reader is also referred to EPA's technical support document contained
in the docket for a more complete discussion of the SIP development and
requirements.
1. Facility Description
The Doe Run-Herculaneum facility was opened in 1892 and is the only
primary lead smelter currently operating in the United States. The
annual total production capacity of the facility is approximately
250,000 tons of refined lead.
The primary lead smelting process begins with lead concentrate. Doe
Run-owned mining and milling operations located in southeastern
Missouri are the primary source of Doe Run-Herculaneum's lead ore and
lead concentrate. Lead ore, typically 45 percent to 50 percent lead by
weight, is mined from underground ore deposits. The ore is crushed and
then processed into lead concentrate at the mills. Lead concentrate
contains approximately 75 percent lead by weight. Lead concentrate was
previously transported from the mines/mills to the Herculaneum smelter
by rail, but since 2002 has been transported exclusively by truck to
Herculaneum. Once delivered to the Herculaneum primary lead smelter,
the process of smelting the lead concentrate into high purity lead can
be divided into three main steps: Sintering, reducing (smelting), and
refining.
Once delivered to Herculaneum, the concentrate is first processed
through the sinter plant. The concentrate is mixed and crushed with
other feedstock materials such as silica, iron ore, and limestone
fluxes. Recycled process material such as returned sinter, blast
furnace slag, and baghouse fume may also be added to this mixture to
produce the sinter feed. A thin layer of sinter feed enters the sinter
machine and is ignited by a series of natural gas burners. A main
sinter feed layer is then laid on top of this ignition layer. This
layered sinter bed enters the updraft portion of the sinter machine,
where air is drawn across the sinter bed from the bottom to the top,
driving the thermal reaction. The lead sulfide contained in the feed is
oxidized, producing lead oxide and releasing sulfur dioxide. Off-gasses
from the sintering process are sent to a baghouse which removes
particulate matter. The off-gasses continue on to the acid plant where
sulfur dioxide is recovered as sulfuric acid. The sinter machine
produces a continuous feed of sinter cake (also called sinter roast)
which is crushed and sorted by size. The larger pieces are transported
to the blast furnace or to temporary storage, while the undersized
pieces return to the mix room to await reprocessing through the sinter
machine.
Smelting takes place in Doe Run-Herculaneum's blast furnaces.
Sinter cake is mixed with coke and other feed materials and transferred
to the top of a furnace. Air feeds through the bottom of the furnace,
resulting in coke combustion. The coke combustion heats the sinter cake
to approximately 3,000 degrees Fahrenheit and produces carbon monoxide.
The carbon monoxide reacts with lead and other metal oxides to produce
molten lead, waste slag, and carbon dioxide. The lead bullion settles
to the bottom of the furnace, where it is tapped into holding pots and
transferred to the drossing area for further refining. The slag (a
sand-like byproduct with small amounts of lead, copper, zinc, and other
materials) floats to the top of the furnace, is tapped off and either
recycled back into the sinter feed or transported to the slag storage
area at the south end of the facility. Impurities are further separated
and removed from the lead in the dross/refinery departments. The lead
bullion from the blast furnace is first transferred to one of the large
drossing kettles where it is allowed to cool. As the bullion cools,
copper, nickel, and other impurities are skimmed from the surface
layer, known as the ``dross.'' Next, the decopperized lead is
transferred to a series of natural gas-heated refining kettles where
additional impurities are removed. Zinc is added to the lead to
facilitate the removal of silver. The zinc-silver dross that forms at
the surface of the kettle is removed and then further processed in
order to recover the silver. Excess zinc is removed by vacuum
distillation and chemical conversion. The resulting lead is more than
99.999 percent pure and is cast into 60-pound and 100-pound pigs, as
well as 1-ton ingots. Precise amounts of other metals may be added to
the molten lead in order to produce lead alloys for specific industrial
uses.
2. Model Selection, Meteorological and Emissions Inventory Input Data
When determining what model would be most appropriate to use for
the Herculaneum SIP control strategy modeling, EPA and MDNR considered
use of Industrial Source Complex Short-Term (ISC3P), CALPUFF, and
AERMOD models. The selected model needed to be able to represent
terrain, emission sources, meteorological conditions, and other
parameters. All three models were deemed adequate to characterize
conditions at Herculaneum. MDNR and EPA also wanted to be able to
perform a model performance evaluation on the selected model using
recent data. A model performance evaluation allows verification that
the model is accurately characterizing emissions from specific
[[Page 58917]]
sources and accurately predicting air concentrations. For Herculaneum,
the model performance evaluation would take advantage of recent
monitored concentration data and filter data. The model would be run
using meteorological data and emissions information from the same time
period as the monitored air concentration and filter data, allowing for
a direct comparison between the modeled results and the monitored
information. Unfortunately, the on-site meteorological station did not
consistently collect a full suite of data over the time period in
question. The data it did collect, supplemented with data from a nearby
met station, was adequate for use in the ISC model. Calculations used
in the AERMOD and CALPUFF models rely on a larger suite of
meteorological parameters and do not work well with supplemental, off-
site information. Therefore, MDNR and EPA concluded that recent
available meteorological data were not of sufficient quantity or
quality to perform a model performance evaluation in the newer CALPUFF
or AERMOD models. ISC3P requires a smaller suite of meteorological data
inputs, can be used to assess concentrations from several types of
sources associated with industrial source complexes, can account for
building downwash, urban or rural dispersion coefficients, flat or
elevated terrain, and averaging periods from one hour to one year. It
was therefore selected as an appropriate model for this SIP
demonstration.
The model performance evaluation which, as described above,
compared modeled results against monitored and filter data, was
conducted using 2005 emission inventory and meteorological information
as inputs into the model, and 2005 monitored concentration and filter
data. Once the model evaluation and refinement was complete, the
attainment demonstration modeling was conducted using quality assured
meteorological data from April 1997-March 1999 and January-March 2005.
These nine quarters include a large block of time over which a range of
meteorological conditions occurred, as well as a more recent quarter of
data. Concentrations modeled over these nine quarters of meteorological
data are therefore representative of an assortment of meteorological
conditions, and using these nine quarters of quality assured data
provides confidence that the SIP control strategy was evaluated over a
variety of meteorological conditions.
As required by Section 172(c)(3) of the CAA, a revised emission
inventory was developed for this SIP revision. In general, 2005 hourly
lead emissions were based upon facility daily production records. Many
of the processes and sources of emissions had not been altered since
the previous SIP and associated emission rates were assumed to be
unchanged. Rates were estimated using equations developed from source
testing at the facility or from published emission factors. In some
instances, the emission equations include meteorological parameters to
account for wind-driven emissions. For more information on these SIP
elements, the reader is referred to the technical support document
developed by EPA, included in the docket for this rulemaking.
3. Modeling Results
Actual value dispersion modeling was conducted to determine whether
the model was performing adequately to pursue attainment demonstration
modeling. This was determined through three comparisons: (1)
Determining the model's ability to replicate monitored daily lead
concentrations, (2) comparing the actual value modeling results with
filter analysis results, and (3) determining the model's ability to
replicate averaged actual monitored lead concentrations. The
meteorological data set used in the actual value/model performance
modeling was developed from data collected in 2005.
The first comparison, evaluating the model output versus the
monitored values on a day-to-day basis, was completed for Broad Street,
Main Street/City Hall, Bluff, and Dunklin High School monitor sites.
Overall, the model performed well and matched general increases and
decreases in daily values. The precise predicted daily concentrations
varied from the measured concentrations. This was attributed to
uncertainties in the meteorological measurements, model algorithms, and
the emission inventory.
The second comparison looked at the filter analysis versus the
model. By combining fingerprint data from the previous SIP with updated
source profiles, the filters were analyzed for the percent contribution
from several facility source categories. This filter analysis source
category percentage contribution profile was compared against the
percentage contribution profile indicated by the modeling. As a result
of these comparisons, the state modelers identified a modeled under-
prediction of sinter building fugitives. This was subsequently
corrected in the modeling. Model results were compiled after the
identified problems were corrected and compared against the filter
analysis. The filter analysis and model results showed reasonable
agreement.
The third comparison, looking at the model's ability to replicate
actual quarterly monitored lead concentrations, also gave favorable
results. The Sherman monitoring location was added to the four
monitoring locations used in the first comparison. The Broad Street
monitor is the monitor located closest to the smelter and is the
monitor that has registered the majority of the exceedances since 2002.
At the Broad Street monitor site the model performed well, over-
predicting at one monitor and under-predicting at the other co-located
monitor, and closely matching the averaged Broad Street site value. The
model over-predicted concentrations at the other monitors. The state
concluded that the model adequately predicted values at Broad Street,
and gave conservative, possibly high, predicted concentrations at the
other monitors. These comparisons showed the model performed adequately
to determine whether the proposed controls would be sufficient to
provide for attainment of the lead NAAQS.
Design value modeling was conducted to identify which sources may
be significant contributors in a hypothetical scenario where all
processes operated for as many hours as possible, and throughput was as
high as possible. The design value modeling was completed for a worst-
case scenario without consideration of the 2007 proposed controls and
without assuming the controls resulting from the previous 2002 SIP.
Results from this worst-case scenario modeling indicated sources or
groups of sources that may significantly contribute to lead
concentrations. Identified source areas included: south-end storage,
all process building fugitives, Baghouse 7/9 stack, Baghouse 8 stack,
unloader area, and in-plant roads. The state then examined the
effectiveness of existing controls and the technological and economic
feasibility for additional controls at these sources.
Finally, the control strategy model was developed. The control
strategy model incorporates all changes made as a result of the actual
value modeling/model refinement runs, and included all control measures
contained in the 2007 SIP. This required application of capture and/or
control efficiencies to a number of emission points, changing stack
parameters to reflect modified stacks, and limitations on process
throughputs and/or hours of operation.
One specific set of control efficiencies included in the control
strategy modeling was attributed to process
[[Page 58918]]
buildings as a result of operating conditions required by a ventilation
study. The Consent Judgment requires Doe Run to conduct a building
ventilation study for the Sinter Building, Blast Furnace Building, and
Refinery Building. Building openings, ventilation sources with either
continuous or varying rates of operation, and a procedure for measuring
inflow into the buildings must be identified within the study. The
study must also include enforceable conditions developed to ensure that
particles emitted within the process buildings are being appropriately
captured by the ventilation systems.
The ventilation study works together with door closure and building
siding inspection requirements to achieve an overall objective, or
control measure, of effective building enclosure. By minimizing
building openings and ensuring adequate ventilation, the buildings will
be operated and maintained in such a fashion as to minimize the escape
of fugitive emissions from the buildings. The SIP requires this overall
building enclosure control measure, and also requires adequate
ventilation in each of the process buildings under the ventilation
study element. The control strategy modeling attributes a control
efficiency to the overall building enclosure control measure, and this
control efficiency is included in all attainment demonstration
calculations. Although the adequate ventilation and overall building
enclosure control measures are required under the SIP, the SIP does not
include all necessary enforceable conditions (such as fan amperages or
flow rates) associated with the ventilation study to ensure that these
ventilation-related control measures are met. Upon MDNR's approval of
the ventilation study and its findings, the enforceable conditions
identified in the study will become part of the Consent Judgment and/or
Work Practices Manual. MDNR asserts that it will adopt and submit these
enforceable conditions to EPA by date certain, which will be no later
than one year following any EPA approval of the plan. See the
``Proposed Actions'' section of this rulemaking for EPA's proposed
approach to address this element of the SIP.
Unless specific hourly or daily operating limitations were applied
to a process or activity, sources at the plant were modeled based on a
quarterly average. Many emission sources at Doe Run do not run
continuously, twenty-four hours a day, seven days a week. However, in
order to account for the variety of meteorological conditions simulated
in the analyses, the model was run using an average emission rate,
calculated assuming 24-hour operation of these sources.
One source where emissions are not expected to be uniform across
all days is roadways. The control strategy modeling attributes a 95
percent control efficiency to paved in-plant roads and paved truck haul
routes external to the plant. This control percentage was modeled
uniformly across all days modeled. Given typical operating conditions,
the Herculaneum smelter generally experiences somewhat less activity on
weekends than on weekdays. The wet sweeper is required to operate a
minimum of Monday through Friday, and the regenerative air sweeper must
operate Monday through Friday as well as any days concentrate is
scheduled for delivery. The state attributed a control efficiency of 95
percent to the sweepers alone. Requirements for a continuously-
operating sprinkler system, truck tarping and truck washing add an
additional layer of emission controls. An average 95 percent control
efficiency was attributed to the paved roads for all days modeled.
Further discussion on road controls may be found in the technical
support document developed by EPA and included in the docket for this
rulemaking.
The resulting maximum predicted quarterly lead concentration from
the state's control strategy modeling was 1.492 [mu]g/m\3\. The 1.492
[mu]g/m\3\ concentration includes a calculated background
concentration. A background concentration is significant due to its
contribution to the total concentration of lead in ambient air. The
lead NAAQS requires the concentration of lead, from all sources of lead
in ambient air, not to exceed 1.5 [mu]g/m\3\. The state emissions
inventory identified the Doe Run smelter and associated activities as
the only lead sources near Herculaneum. The state then developed a
background concentration to account for the contribution to monitored
concentrations from distant sources of lead, any naturally occurring
lead in the atmosphere, and sources of lead not captured by the
Herculaneum lead emissions inventory. It is also possible that the
calculated background includes secondary (e.g., re-entrained historical
lead deposition from the plant) or primary impacts from the smelter and
associated activities, some of which may also be captured by the
Herculaneum lead emissions inventory. The state believes that in this
situation, the background concentration would be over-estimated and
would provide a conservative estimate for the attainment demonstration
analysis.
The background concentration was calculated by examining
concentrations at three geographically dispersed Herculaneum air
monitors (Ursaline--distant south, Bluff--proximate north, and High
School--middle scale northwest). MDNR identified days when
meteorological data indicated the wind was not blowing from the smelter
toward the individual monitors. The monitored concentrations associated
with these days were then averaged, resulting in a background
concentration of 0.063 [mu]g/m\3\. Further detail on how the background
concentration was calculated may be found in the technical support
document developed by EPA and included in the docket for this
rulemaking.
4. Control Strategy
In order to bring Herculaneum back into attainment of the lead
NAAQS, MDNR developed a control strategy for Doe Run-Herculaneum. The
control strategy requires Doe Run-Herculaneum to implement measures to
control emissions from five general areas: building fugitives, baghouse
and stack emissions, storage piles, transportation, and emissions
reductions through production volume and hours of operation
restrictions. A brief description of controls associated with each
follows below.
Several control measures must be implemented to reduce escape of
process building fugitive emissions to the outside air: (1) Automatic
door closure mechanization and lock-out procedures, (2) a requirement
for installation of a south door and specific door closure procedures
for the Railcar Tipper Building, and (3) building siding inspections
and maintenance work practices. As discussed in the ``Modeling
Results'' portion of this proposed rulemaking, a study will establish
ventilation parameters, such as minimum fan amperages, necessary to
ensure particle capture by the ventilation systems or particle capture
within the buildings, and compliance with ventilation specifications
resulting from the aforementioned study and specifications will be
required under the Consent Judgment and/or Work Practices Manual. In
addition, fugitive emissions from specific processes within buildings
will also be reduced through a number of new controls: (1) Sinter wheel
ventilation enclosure, (2) blast furnace doghouse ventilation
improvement and redesign of hoods servicing the front of the furnace,
(3) automated blast furnace tuyure controls and interlock control
system, and (4) relocation of blast furnace 1 to reduce ductwork,
reduce length of the charge
[[Page 58919]]
belt, and potentially increase ventilation flow rates.
Controls specific to baghouses and stack emissions include: (1)
Enclosure of the dust handling sections of the Carrier Cooler Baghouse,
(2) installation of an alarm system for Number 5 Baghouse fans, (3)
pleated filter installation and use in Number 7 & 9 Baghouse, (4) new
bags and installation and use of reverse flow technology for bag
cleaning in Number 3 Baghouse, and (5) visual monitoring of kettle heat
stacks and work practices to address kettle failures. An additional
feature of the baghouses is an increased stack height for Number 7 & 9
Baghouse, and Number 8 Baghouse stacks. (These stack height increases
remain below good engineering practice heights.)
Emissions from storage piles and associated materials handling will
be reduced through: (1) Partial enclosure of the concentrate delivery
area and full enclosure of the sinter loading area, (2) utilization of
drop sleeves, (3) minimum moisture content requirements for concentrate
and fume, and (4) wetting and chemical stabilization of storage piles.
Transportation-related emissions will be reduced through: (1) Use
of street sweeping technologies on paved roads both inside and outside
of the plant, (2) in-plant sprinklers, (3) wetting and chemical
stabilization of the slag haul road, and (4) haul truck tarp use, tarp
maintenance, and concentrate truck washing before leaving the facility.
Finally, the May 2007 Consent Judgment and January 2007 Work
Practices Manual also include process throughput limitations and hours
of operation limitations. Process limits are specified for certain
materials handing operations. Twenty-four hour maximum allowable and/or
quarterly maximum allowable throughputs are also specified for sinter,
blast furnace, dross, and refinery production processes. Additional
requirements are contained in the Consent Judgment and Work Practices
Manual submitted as part of this SIP and contained in this rule docket.
EPA requires in 40 CFR part 51, subpart N, that a compliance
schedule generally provide for compliance as soon as practicable, but
no later than the attainment date included in the plan. The final SIP
call required the state to submit a revised SIP no later than April 7,
2007 (no later than a year after the final SIP call was signed), and
for Herculaneum to attain the lead NAAQS no later than April 7, 2008.
EPA afforded only a year for development of the plan, and one year
after that for implementation of controls. This was done because lead
is a significant public health concern, technical information from past
SIP actions was available, and early discussions between the state and
Doe Run about new controls had taken place. EPA did not believe that
less than a year was appropriate for development of the plan due to the
substantial amount of work required to develop a SIP revision. In order
to develop a revised lead SIP, the state would need to develop a
revised emissions inventory to characterize the plant's current
conditions and operations, create a model to reflect conditions at
Herculaneum, evaluate and refine the model, determine where new
controls might reduce emissions, evaluate the feasibility of any such
controls, and develop a control strategy that modeled attainment of the
standard. In recognition of the time involved with each of these
efforts, and the amount of time it takes to complete large construction
projects, EPA believed that the deadlines contained in the SIP call
would require attainment as expeditiously as practicable.
A compliance schedule for implementation of controls is detailed in
the Consent Judgment. All controls described above were included in the
attainment demonstration modeling (also called the control strategy
modeling), with the exception of control measures the state felt
provided reassurances that emissions would be reduced but did not feel
warranted its own control efficiency. The state's attainment
demonstration modeling predicted a maximum quarterly concentration of
1.492 ug/m\3\. Further discussion of the individual controls may be
found in EPA's technical support document included in this docket. The
Consent Judgment schedule provides for compliance as expeditiously as
practicable, but no later than April 7, 2008. EPA believes that the
control strategy and the compliance schedule contained in the control
strategy, with the exception of the ventilation controls discussed in
the ``Proposed Actions'' portion of this document, provide for
attainment as expeditiously as practicable, and otherwise meet the
applicable requirements of the Clean Air Act.
5. Reasonably Available Control Measures (RACM) Including Reasonably
Available Control Technology (RACT)
Section 172(c)(1) of the CAA requires nonattainment areas to
implement all RACM, including emissions reduction through the adoption
of RACT, as expeditiously as practicable. EPA interprets this as
requiring all nonattainment areas to consider all available controls
and to implement all measures that are determined to be reasonably
available, except that measures which will not assist the area to more
expeditiously attain the standard are not required to be implemented.
See 58 FR 67751, December 22, 1993, for a discussion of this
interpretation as it relates to lead.
In the April 14, 2006, SIP call, EPA did not list a new RACT
analysis as a required element of the SIP submittal. Even though not
required by the 2006 SIP call, a RACT/RACM analysis is still included
with the 2007 SIP submittal. No additional RACT measures were
identified that would expedite attainment or reasonable further
progress, and the plant has not changed significantly from when the
previous RACT/RACM evaluation was completed. Some previously
implemented RACT/RACM measures, i.e., types of controls, were
strengthened through incorporation of more detailed, enforceable work
practices in the Work Practices Manual. Although not directly relevant
to RACT/RACM, we note that the Herculaneum primary lead smelter is also
subject to 40 CFR Part 63 subpart TTT, the Federal MACT standard for
Primary Lead Smelters. Subpart TTT requires the development and use of
standard operating procedures manuals for all baghouses controlling
process, process fugitive, or fugitive lead dust emissions.
Dispersion modeling analysis was conducted to determine if the
controls required by the 2007 Consent Judgment control strategy would
be sufficient to bring the area into attainment of the standard. The
dispersion modeling submitted by the state showed attainment of the 1.5
ug/m\3\ standard, demonstrating that the control strategy is adequate
to bring the area into attainment of the standard. In terms of
expeditious attainment we again note that the time between the SIP
submission deadline and the attainment date is only one year, so that
additional measures which could be implemented within that year and
achieve reductions before the end of that year would be even less
likely. For the reasons stated above, EPA proposes to find that no
additional measures will expedite attainment and that the RACT/RACM
requirement is met.
6. Reasonable Further Progress (RFP)
Section 172(c)(2) of the CAA requires SIPs to provide for
Reasonable Further Progress (RFP) as defined in section 171(1) of the
CAA. Section 171(1) defines RFP as annual incremental reductions in
emissions of the relevant air pollutants as required by Part D, or
[[Page 58920]]
emission reductions that may reasonably be required by EPA to ensure
attainment of the applicable NAAQS by the applicable date. Part D does
not include specific RFP requirements for lead.
MDNR has demonstrated RFP as required under section 172(c)(2) of
the CAA. Doe Run is subject to a compliance schedule for implementing:
(1) Installation of emission control equipment, (2) enclosure and
ventilation projects to reduce lead emissions, (3) process throughput
restrictions and hours of operation limitations, and (4) work practice
standards. These are but a few of the SIP controls that are enforceable
through the Consent Judgment and/or the Work Practices Manual. Given
that all controls contained in the control strategy were required to be
implemented by April 7, 2008, to provide for attainment by April 7,
2008, EPA does not believe additional incremental reductions are
necessary to meet the RFP requirement. EPA also notes that, since all
of the new controls in the SIP were required to be implemented within
one year of development of the control strategy (April 2007 to April
2008), and that these controls have been demonstrated to be adequate
for attainment, we believe that these controls represent the annual
reductions necessary for RFP and attainment.
7. New Source Review (NSR)
Within the CAA, Part D of Title I requires SIP submittals to
include a permit program for the construction and operation of new and
modified major stationary sources. The current definition of
nonattainment areas in Missouri, which for lead includes the city of
Herculaneum, Missouri, is provided in Missouri rule 10 CSR 10-6.020.
For installations in a nonattainment area, Missouri rule 10 CSR 10-
6.060 requires a permit for construction of, or major modification to,
an installation with potential to annually emit one hundred (100) tons
or more of a nonattainment pollutant, or a permit for a modification at
a major source with potential to annually emit one thousand two hundred
(1,200) pounds of lead. The SIP call did not require revision to these
rules. Both rules have been previously approved by EPA as part of the
SIP, as meeting the requirements of section 173 of the Clean Air Act,
and EPA implementing rules in 40 CFR 51.165.
8. Contingency Measures
As required by CAA section 172(c)(9), the SIP submittal includes
contingency measures to be implemented if EPA determines that
Herculaneum has failed to make reasonable further progress, or if the
area fails to attain the NAAQS by April 7, 2008, as set forth in the
SIP call (71 FR 19432). If the area has an exceedance of the NAAQS
during any quarter following the April 7, 2008, attainment date, the
contingency measures will be implemented according to the schedule
outlined in the May 2007 Consent Judgment, upon written notification of
violation from MDNR. MDNR may also require implementation of
contingency measures if the control strategy projects are not completed
as required in the Consent Judgment.
Within six months of receipt of such a notice, Doe Run is required
to complete contingency measure (a) enclosure of the sinter plant
``pugger,'' and contingency measure (b) paving of the slag haul road
from the north end of the blast furnace to the refinery dock. Following
implementation of these two projects, if any quarter exceeds the
standard or Doe Run fails to make reasonable further progress (in this
instance, timely implementation of control measures), MDNR will notify
Doe Run and contingency measure (c) rerouting of the kettle heat stacks
to the main stack, is required to be completed within 18 months of
receipt of the notice.
In addition, if an exceedance of the quarterly lead NAAQS occurs,
the quarterly production limit for refined lead is required to be
reduced to 95% of the actual production during the exceedance quarter.
The refined lead production limit will be reduced by an additional 5%
below actual production for each subsequent quarter in which there is
an exceedance, to a minimum production of 35,000 tons of refined lead
per calendar quarter. In the event that all monitors show attainment in
a quarter following a production decrease, the production level for
refined lead may be increased by 5% of the attainment quarter's actual
production provided that Doe Run implements additional control measures
prior to increasing the production level. Doe Run must demonstrate to
MDNR that these control measures reduce impacts on air quality to an
equal or greater extent than the increased production limit will
increase impacts on air quality. In addition, any substitution of
control measures is subject to EPA approval through the SIP revision
process described below. Production may increase to a maximum of 62,500
tons per calendar quarter (the level assumed in the attainment
demonstration modeling), if the area continues to monitor attainment of
the NAAQS.
The Consent Judgment further outlines two additional contingency
measures to be implemented in the event that exceedances occur after
implementation of the contingency measures described above. Contingency
measure (d) requires implementation of contingency measures identified
as a result of a technological study for fugitive dust control. These
not-yet identified measures would be implemented within a time frame to
be determined by Doe Run and MDNR. Contingency measure (e) would
require installation of dedicated ventilation to the sinter plant or
implementation of Flubor(copyright) technology at the Herculaneum
facility. This contingency would be required if an exceedance is
monitored or Doe Run fails to make reasonable further progress after
implementation of contingency measure (c) routing of kettle heat stacks
to the main stack, and contingency measure (d) contingencies identified
by the fugitive dust control study to be implemented according to a
currently undefined schedule.
Section 172(c)(9) of the Act provides that contingency measures
must be capable of implementation without any further action by the
state or EPA. While EPA supports implementation of the activities
described in contingency measures (d) and (e), because these two
projects do not contain specific requirements and/or associated
deadlines, EPA does not consider them contingency measures under
section 172(c)(9) of the Act. EPA therefore proposes to only include
contingency measures (a) enclosure of the pugger, (b) paving of haul
road, (c) rerouting of kettle heat stacks, and the percent production
cuts as contingency measures under the Federally-enforceable SIP.
Doe Run must notify MDNR within 10 days of completion of any
contingency measure. Sixty days after completion, Doe Run will propose
an additional quantified contingency measure to be added to the Consent
Judgment, which will become part of the Consent Judgment and fully
enforceable upon approval by MDNR. These additional contingency
measures will also be subject to EPA approval as part of the SIP. Doe
Run may also substitute new control(s) for the above contingency
measure(s) if Doe Run identifies and demonstrates to MDNR and EPA's
satisfaction the alternate control measure(s) would achieve equal or
greater air quality improvements as compared to the contingency
measures currently outlined in the Consent Judgment.
[[Page 58921]]
Changes to contingency measures would require a public hearing at
the state level and EPA approval as a formal SIP revision. Until such
time as EPA approves any substitute measure, the measure included in
the approved SIP will be the enforceable measure. EPA does not intend
to approve any substitutions which cannot be implemented in the same
timeframe as the original. These measures will help ensure compliance
with the lead NAAQS as well as meet the requirements of Section
172(c)(9) of the CAA.
9. Enforceability
As specified in section 172(c)(6) and section 110(a)(2)(A) of the
CAA, and 57 FR 13556, all measures and other elements in the SIP must
be enforceable by the state and EPA. Enforceable documents included in
Missouri's SIP submittal are the May 2007 Consent Judgment and January
2007 Work Practices Manual. The Consent Judgment contains all control
and contingency measures with enforceable dates for implementation. The
only exception relates to the enforceable requirements for the
ventilation controls, discussed above and in section III below. The
Consent Judgment also includes monitoring, recordkeeping, and reporting
requirements to ensure that the control and contingency measures are
met. The Work Practices Manual includes these, as well as specific
operating procedures and additional reporting requirements. The state
adopted both documents into Missouri's state regulations on April 26,
2007, making them state-enforceable. Upon EPA approval of the SIP
submission, both documents will become state and Federally enforceable,
and enforceable by citizens under section 304 of the Act.
We note that the Consent Judgment also contains provisions for
stipulated penalties and sanctions should Doe Run fail to comply with
provisions of the Consent Judgment or Work Practices Manual. EPA is not
bound by the state's Consent Judgment penalties, and would enforce
against violations of these documents under section 113 of the Clean
Air Act or other Federal authorities, rather than the Consent Judgment,
if it approves the Consent Judgment and Work Practices Manual into the
SIP.
III. Proposed Action
In a July 9, 1992, memorandum from John Calcagni, EPA discussed the
options for actions on SIP submissions. One such option, conditional
approval, is authorized under section 110(k)(4) of the CAA and is
available where a rule strengthens the SIP even though the entire
submittal does not meet all applicable requirements. A conditional
approval requires a commitment from the state to adopt specific
enforceable measures within a specific timeframe. The measures must be
adopted no later than one year from the date of EPA's final conditional
approval. EPA is proposing to grant conditional approval for Missouri's
attainment demonstration SIP for the lead National Ambient Air Quality
Standard nonattainment area of Herculaneum, Missouri. By date certain,
which will be no later than one year following any EPA approval of the
plan, the state asserts that it will adopt and submit to EPA
enforceable measures related to ventilation of the process buildings
described previously.
As described in this proposed rulemaking's ``Modeling Results''
section, one set of control measures contained in this SIP submittal
requires creation of enforceable conditions to ensure appropriate
building ventilation for particle capture. MDNR has not approved
enforceable conditions such as fan amperages or flow rates related to
this control. Therefore, although the SIP includes enforceable measures
(building enclosure and adequate ventilation measures) related to this
control, the ventilation requirements do not currently contain all
necessary enforceable conditions to ensure that the provisions are met.
The ventilation study and resulting reduction in building fugitive
emissions is a significant element of the proposed control strategy,
and these projected emissions reductions contribute significantly to
the control strategy modeling showing attainment. EPA does not believe
it is appropriate to give full approval to the SIP until the
ventilation study and associated enforceable conditions are submitted
by the state, reviewed by EPA, and made available for public comment.
EPA proposes conditional approval of the SIP as it provides
substantial progress toward improving air quality, and the state
asserts that it will adopt and submit the missing elements to EPA by
date certain, which will be no later than one year following any EPA
approval of the plan. If EPA reviews and finds the ventilation control
conditions adequate, EPA will publish and take comment on a
supplemental proposal relating to the ventilation control conditions.
This supplemental proposal may include a proposal to fully approve the
SIP.
If the state does not submit the control strategy element described
above by date certain, which will be no later than one year following
any EPA approval of the plan, and EPA takes final action to
conditionally approve the revised lead SIP, the conditional approval
will convert to a disapproval, as provided by section 110(k)(4) of the
Act. In that instance, all portions of the revision not related to the
ventilation study portion of the control strategy will remain in
effect. However, disapproval of the ventilation study portion will
start a clock for implementation of Clean Air Act sanctions under
section 179(b), and a clock for promulgation of a Federal
implementation plan under section 110(c)(1) of the Act.
IV. Statutory and Executive Order Reviews
Under the Clean Air Act, the Administrator is required to approve a
SIP submission that complies with the provisions of the Act and
applicable Federal regulations. 42 U.S.C. 7410(k); 40 CFR 52.02(a).
Thus, in reviewing SIP submissions, EPA's role is to approve state
choices, provided that they meet the criteria of the CAA. Accordingly,
this proposed action merely approves state law as meeting Federal
requirements and does not impose additional requirements beyond those
imposed by state law. For that reason, this proposed action:
Is not a ``significant regulatory action'' subject to
review by the Office of Management and Budget under Executive Order
12866 (58 FR 51735, October 4, 1993);
Does not impose an information collection burden under the
provisions of the Paperwork Reduction Act (44 U.S.C. 3501 et seq.);
Is certified as not having a significant economic impact
on a substantial number of small entities under the Regulatory
Flexibility Act (5 U.S.C. 601 et seq.);
Does not contain any unfunded mandate or significantly or
uniquely affect small governments, as described in the Unfunded
Mandates Reform Act of 1995 (Public Law 104-4);
Does not have Federalism implications as specified in
Executive Order 13132 (64 FR 43255, August 10, 1999);
Is not an economically significant regulatory action based
on health or safety risks subject to Executive Order 13045 (62 FR
19885, April 23, 1997);
Is not a significant regulatory action subject to
Executive Order 13211 (66 FR 28355, May 22, 2001);
Is not subject to requirements of Section 12(d) of the
National Technology Transfer and Advancement Act of 1995 (15 U.S.C. 272
note) because application of those requirements would
[[Page 58922]]
be inconsistent with the Clean Air Act; and
Does not provide EPA with the discretionary authority to
address, as appropriate, disproportionate human health or environmental
effects, using practicable and legally permissible methods, under
Executive Order 12898 (59 FR 7629, February 16, 1994).
In addition, this rule does not have tribal implications as specified
by Executive Order 13175 (65 FR 67249, November 9, 2000), because the
SIP is not approved to apply in Indian country located in the state,
and EPA notes that it will not impose substantial direct costs on
tribal governments or preempt tribal law.
List of Subjects in 40 CFR Part 52
Environmental protection, Air pollution control, Carbon monoxide,
Incorporation by reference, Intergovernmental relations, Lead, Nitrogen
dioxide, Ozone, Particulate matter, Reporting and recordkeeping
requirements, Sulfur oxides, Volatile organic compounds.
Dated: September 30, 2008.
John B. Askew,
Regional Administrator, Region 7.
[FR Doc. E8-23877 Filed 10-7-08; 8:45 am]
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